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Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance

Received: 19 May 2016     Published: 19 May 2016
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Abstract

With nano-alumina modified by the fat acid as an inorganic template for making pores, a new kind of porous resin particle with the large surface was synthesized by emulsion polymerization. Moreover, the sulfonated polystyrene resin was fluorinated to increase its acid strength up to Ho 8.6 and the acid amount of 4.1mmol/g. The ratio of butane to water was increased by packing the catalytic resin with the fixed beds of four stages. Under reaction temperature of 168-174°C, butane to water ratio of 2 mol/mol and WHSV1.0 h-1, hydration reaction conversion was over 15 wt%, with the butyl alcohol selectivity of 99 wt% and a good thermal stability.

Published in Science Discovery (Volume 4, Issue 2)
DOI 10.11648/j.sd.20160402.23
Page(s) 137-141
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2016. Published by Science Publishing Group

Keywords

Butene Hydration, Pores, Acid Resin, Catalyst, Reaction Performance

References
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[3] 何英华,王苑,杨玉和,等。C4烃资源综合利用技术进展[J],化工技术与开发,2012,41(3):28-34。
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[7] 董炳利,周金波,王燕飞,等.碳四烃中异丁烯水合制叔丁醇技术进展[J],应用化工,2012,41(4):693-696。
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Cite This Article
  • APA Style

    Cai Jian-guo, Shi Hong-yan, Zhu Zhi-rong, Shi Xiao-li. (2016). Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance. Science Discovery, 4(2), 137-141. https://doi.org/10.11648/j.sd.20160402.23

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    ACS Style

    Cai Jian-guo; Shi Hong-yan; Zhu Zhi-rong; Shi Xiao-li. Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance. Sci. Discov. 2016, 4(2), 137-141. doi: 10.11648/j.sd.20160402.23

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    AMA Style

    Cai Jian-guo, Shi Hong-yan, Zhu Zhi-rong, Shi Xiao-li. Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance. Sci Discov. 2016;4(2):137-141. doi: 10.11648/j.sd.20160402.23

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  • @article{10.11648/j.sd.20160402.23,
      author = {Cai Jian-guo and Shi Hong-yan and Zhu Zhi-rong and Shi Xiao-li},
      title = {Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance},
      journal = {Science Discovery},
      volume = {4},
      number = {2},
      pages = {137-141},
      doi = {10.11648/j.sd.20160402.23},
      url = {https://doi.org/10.11648/j.sd.20160402.23},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.sd.20160402.23},
      abstract = {With nano-alumina modified by the fat acid as an inorganic template for making pores, a new kind of porous resin particle with the large surface was synthesized by emulsion polymerization. Moreover, the sulfonated polystyrene resin was fluorinated to increase its acid strength up to Ho 8.6 and the acid amount of 4.1mmol/g. The ratio of butane to water was increased by packing the catalytic resin with the fixed beds of four stages. Under reaction temperature of 168-174°C, butane to water ratio of 2 mol/mol and WHSV1.0 h-1, hydration reaction conversion was over 15 wt%, with the butyl alcohol selectivity of 99 wt% and a good thermal stability.},
     year = {2016}
    }
    

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  • TY  - JOUR
    T1  - Porous Resin Catalyst with Strong Acidity for Hydration Reaction of Butane and Its Catalytic Performance
    AU  - Cai Jian-guo
    AU  - Shi Hong-yan
    AU  - Zhu Zhi-rong
    AU  - Shi Xiao-li
    Y1  - 2016/05/19
    PY  - 2016
    N1  - https://doi.org/10.11648/j.sd.20160402.23
    DO  - 10.11648/j.sd.20160402.23
    T2  - Science Discovery
    JF  - Science Discovery
    JO  - Science Discovery
    SP  - 137
    EP  - 141
    PB  - Science Publishing Group
    SN  - 2331-0650
    UR  - https://doi.org/10.11648/j.sd.20160402.23
    AB  - With nano-alumina modified by the fat acid as an inorganic template for making pores, a new kind of porous resin particle with the large surface was synthesized by emulsion polymerization. Moreover, the sulfonated polystyrene resin was fluorinated to increase its acid strength up to Ho 8.6 and the acid amount of 4.1mmol/g. The ratio of butane to water was increased by packing the catalytic resin with the fixed beds of four stages. Under reaction temperature of 168-174°C, butane to water ratio of 2 mol/mol and WHSV1.0 h-1, hydration reaction conversion was over 15 wt%, with the butyl alcohol selectivity of 99 wt% and a good thermal stability.
    VL  - 4
    IS  - 2
    ER  - 

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Author Information
  • Jiangsu Hyper Functional Materials Co. Ltd., Suzhou, China

  • Jiangsu Hyper Functional Materials Co. Ltd., Suzhou, China

  • Jiangsu Hyper Functional Materials Co. Ltd., Suzhou, China

  • Jiangsu Hyper Functional Materials Co. Ltd., Suzhou, China

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